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Structure and properties of TeO2 containing calcium borophosphate glasses

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39897141" target="_blank" >RIV/00216275:25310/13:39897141 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1166/asem.2013.1338" target="_blank" >http://dx.doi.org/10.1166/asem.2013.1338</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1166/asem.2013.1338" target="_blank" >10.1166/asem.2013.1338</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Structure and properties of TeO2 containing calcium borophosphate glasses

  • Original language description

    Calcium borophosphate glasses doped with TeO2 were studied in the compositional series (100-x)[0.5CaO-0.1B2O3-0.4P2O5]-xTeO2 in a concentration range of x = 0-30 mol% TeO2. DTA studies showed that all of glasses crystallize on heating within the temperature region of 600-750°C and the surface nucleation mechanism prevails over the internal one. Compounds formed by crystallization were BPO4, Ca2P2O7 and Ca4P6O19. Glass transition temperature and crystallization temperature decrease with increasing TeO2 content as well as the thermal stability of glasses. The addition of TeO2 to the starting calcium borophosphate glass also resulted in a gradual decrease of the chemical durability of glasses. According to the Raman spectra, TeO2 is incorporated in the structural network in the form of TeO3 and TeO4 structural units and the ratio of TeO4/TeO3 increases with increasing TeO2 content in the glasses.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    JH - Ceramics, fire-proof materials and glass

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Advanced Science, Engineering and Medicine

  • ISSN

    2164-6627

  • e-ISSN

  • Volume of the periodical

    neuveden

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

    1-6

  • UT code for WoS article

  • EID of the result in the Scopus database