Self-assembled sensor based on boron-doped diamond and its application in voltammetric analysis of picloram
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39897900" target="_blank" >RIV/00216275:25310/14:39897900 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/03067319.2013.879300" target="_blank" >http://dx.doi.org/10.1080/03067319.2013.879300</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/03067319.2013.879300" target="_blank" >10.1080/03067319.2013.879300</a>
Alternative languages
Result language
angličtina
Original language name
Self-assembled sensor based on boron-doped diamond and its application in voltammetric analysis of picloram
Original language description
A self-assembled sensor based on a boron-doped diamond was investigated as a sensitive tool for voltammetric analysis of a member of a pyridine herbicide family - picloram. A cyclic voltammetry and a differential pulse voltammetry were applied for investigation of the voltammetric behavior and quantification of this herbicide. Picloram yielded one well-developed irreversible oxidation signal at a very positive potential about +1.5 V vs. Ag/AgCl/3 mol L-1 KCl electrode in an acidic medium and 1 mol L-1 H2SO4 was chosen as a suitable supporting electrolyte. Operating parameters of differential pulse voltammetry were optimized and the proposed voltammetric method provided a high repeatability (a relative standard deviation of 20 repeated measurements at aconcentration level of picloram of 50 ?mol L-1 equaled to 2.58%), a linear concentration range from 2.5 to 90.9 ?mol L-1 and a low limit of detection (LD = 1.64 ?mol L-1). Practical usefulness of the "environmentally-green" electrochemic
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/EE2.3.30.0021" target="_blank" >EE2.3.30.0021: Strenthening of Research and Development Teams at the University of Pardubice</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
International Journal of Environmental Analytical Chemistry
ISSN
0306-7319
e-ISSN
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Volume of the periodical
94
Issue of the periodical within the volume
9
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
943-953
UT code for WoS article
000340248000008
EID of the result in the Scopus database
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