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Zwitterionic monolithic capillary columns for hydrophilic interaction chromatography

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39897973" target="_blank" >RIV/00216275:25310/14:39897973 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Zwitterionic monolithic capillary columns for hydrophilic interaction chromatography

  • Original language description

    MEDSA - N,N-dimethyl-N-metacryloxyethyl-N-(3-sulfopropyl)ammonium betaine as a zwitterionic polar functional monomer in combination with seven crosslinking monomers were used for preparation of capillary monolithic columns suitable for separation of polar compounds in hydrophilic interaction chromatography (HILIC). Ethylene dimethacrylate, tetramethylene dimethacrylate, hexamethylene dimethacrylate, dioxyethylene dimethacrylate, pentaerythritole triacrylate, bisphenol A dimethacrylate, and bisphenol A glycerolate dimethacrylate were used as crosslinking monomers (Fig 1). Columns prepared with dioxyethylene dimethacrylate and bisphenol A glycerolate dimethacrylate showed the efficiency up to 70 000 N/m. Columns provide good repeatability of elution volumes with relative standard deviations lower than 1.3 % on both types of columns. Dual retention mechanism allows the separation in HILIC and RP mode. Capillary monolithic columns, id 0.53 mm, were used in the first dimension of the two-di

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP206%2F12%2F0398" target="_blank" >GAP206/12/0398: Two-dimensional separations in liquid media</a><br>

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    CECE 2014: 11th International Interdisciplinary Meeting on Bioanalysis

  • ISBN

    978-80-904959-2-0

  • ISSN

  • e-ISSN

  • Number of pages

    3

  • Pages from-to

    399-401

  • Publisher name

    Ústav analytické chemie AV ČR, v. v. i.

  • Place of publication

    Brno

  • Event location

    Brno

  • Event date

    Oct 20, 2014

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article