Silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine - characterization of this primary explosive
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898360" target="_blank" >RIV/00216275:25310/14:39898360 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/14:00434654
Result on the web
<a href="http://dx.doi.org/10.1002/prep.201300109" target="_blank" >http://dx.doi.org/10.1002/prep.201300109</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/prep.201300109" target="_blank" >10.1002/prep.201300109</a>
Alternative languages
Result language
angličtina
Original language name
Silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine - characterization of this primary explosive
Original language description
A new primary explosive - the silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine (AgDANT) - was synthesized and characterized. AgDANT was prepared with a 97% yield and characterized by IR, single crystal X-ray diffraction and DTA. The crystal density of AgDANT is 2.530 g?cm-3 and the molecule consists of a centro-symmetric dimer with a high degree of planarity. The intramolecular Ag-Ag distance is relatively low (331 pm) and can be considered as a strong argentophilic interaction. AgDANT is non-hygroscopic and its solubility in water (1.27 mg in 100 ml at 23°C) is on a similar level of solubility to that of silver azide. The sensitivity of AgDANT to impact is slightly higher than that for MF, sensitivity to friction is the same as for LA, and sensitivity to electric discharge is between that for LS and MF. Initiation efficiency of AgDANT was tested in electric detonators and compared to dextrinated lead azide (initiation efficiency of AgDANT is 40 mg for PETN secondary charge).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Propellants Explosives Pyrotechnics
ISSN
0721-3115
e-ISSN
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Volume of the periodical
39
Issue of the periodical within the volume
2
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
251-259
UT code for WoS article
000334613000015
EID of the result in the Scopus database
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