Structural diversity of two 1,2,4-triazole based N-heterocyclic carbene complexes of silver(I)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898438" target="_blank" >RIV/00216275:25310/14:39898438 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.inoche.2014.08.019" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2014.08.019</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.inoche.2014.08.019" target="_blank" >10.1016/j.inoche.2014.08.019</a>

Result language
angličtina
Original language name
Structural diversity of two 1,2,4-triazole based N-heterocyclic carbene complexes of silver(I)
Original language description
Two silver(I) complexes of the [(NHC)(2)Ag]Y-+(-) type bearing two different triazole-based N-heterocyclic carbene (NHC) ligands, [1-tert-butyl-4-(2-methoxyphenyl)-3-phenyl-1H-1,2,4-triazol-4-ium-5-ylidene and 1 -tert-butyl-4-(4-methylphenyl)-3-phenyl-1H-1,2,4-triazol-4-ium-5-ylidene], were synthesized according to the modified 'silver salt method. The characterization of the respective complexes in solution by NMR spectroscopy, as well as in solid state by X-ray diffraction techniques, revealed the formation of two different complexes with either an anti or a syn geometry.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F12%2F0223" target="_blank" >GAP207/12/0223: Hybrid ligands for low valent metal centres stabilization/specific activation.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)