Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898441" target="_blank" >RIV/00216275:25310/14:39898441 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.poly.2014.05.005" target="_blank" >http://dx.doi.org/10.1016/j.poly.2014.05.005</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.poly.2014.05.005" target="_blank" >10.1016/j.poly.2014.05.005</a>

Result language

angličtina

Original language name

Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties

Original language description

Five polymeric Mn(II) complexes with bridging carboxylato groups were prepared and structurally characterized. The bridging carboxylato ligand in double-chain coordination polymeric structures of [Mn(mu-3-NO(2)bz)(2) (bipy)](n)center dot nH(2)O, [Mn(mu-3,5-(NO2)(2)bz)(2)(bipy)](n), [Mn(mu-5-(NO2)sal)(2)(bipy)](n), and [Mn(mu-5-(NO2)sal)(2)(phen)](n), where 3-NO(2)bz(-) = 3-nitrobenzoate, 3,5-(NO2)(2)bz(-) = 3,5-dinitrobenzoate, 5-(NO2)sal(-) = 5-nitrosalicylate, bipy = 2,2'-bipyridine and phen = 1,10-phenanthroline, exhibits the syn-anti bidentate bridging mode. The Mn(II) atom in the coordination polymer [Mn(mu-4-NO(2)bz)(4-NO(2)bz)(phen)(H2O)](n), where 4-NO(2)b(z) = 3-nitrobenzoate, is coordinated by terminal carboxylato groups in the syn monodentate mode but two Mn(II) atoms are connected with bridging 4-nitrobenzoate ligands in the anti-anti bidentate bridging mode. The magnetic susceptibility and magnetization data confirm that weak exchange interactions of an antiferromagnetic n

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

79

Issue of the periodical within the volume

September

Country of publishing house

GB - UNITED KINGDOM

Number of pages

9

Pages from-to

129-137

UT code for WoS article

000340313800016

EID of the result in the Scopus database

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