Reactivity of low-oxidation state tin compounds: an overview of the benefits of combining DFT Theory and experimental NMR spectroscopy
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898451" target="_blank" >RIV/00216275:25310/14:39898451 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1139/cjc-2013-0521" target="_blank" >http://dx.doi.org/10.1139/cjc-2013-0521</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1139/cjc-2013-0521" target="_blank" >10.1139/cjc-2013-0521</a>
Alternative languages
Result language
angličtina
Original language name
Reactivity of low-oxidation state tin compounds: an overview of the benefits of combining DFT Theory and experimental NMR spectroscopy
Original language description
The reactivity and complexation properties of dicoordinated Sn(II) and Sn(0) compounds are reviewed. The (dominant) electrophilicity of the stannylenes was confirmed and quantified through density functional theory (DFT) based reactivity indices. For these compounds, combining theoretical DFT calculations and experimental nuclear magnetic resonance (NMR) spectroscopic results has evidenced their potential to undergo pi-complexation from aromatic pi clouds in addition to significantly stronger sigma-complexation. Moreover, their potential as Lewis bases was scrutinized in their interactions and reactions with iron and tungsten carbonyl Lewis acids. Finally, a prospective comparison of the reactivity of divalent stannylenes and stannylones, with a 0 oxidation state at the Sn atom, is presented.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F12%2F0223" target="_blank" >GAP207/12/0223: Hybrid ligands for low valent metal centres stabilization/specific activation.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Canadian Journal of Chemistry - Revue Canadienne de Chimie
ISSN
0008-4042
e-ISSN
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Volume of the periodical
92
Issue of the periodical within the volume
6
Country of publishing house
CA - CANADA
Number of pages
15
Pages from-to
447-461
UT code for WoS article
000343115500005
EID of the result in the Scopus database
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