Reactivity of a C,N-chelated stannylene with chalcogens

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F09%3A10000510" target="_blank" >RIV/00216208:11310/09:10000510 - isvavai.cz</a>

Alternative codes found

RIV/00216275:25310/09:00008660

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Reactivity of a C,N-chelated stannylene with chalcogens

Original language description

The stannylene {2-[(CH3)(2)NCH2]C6H4}(2)Sn (1) was reacted with oxygen, sulfur, selenium, tellurium, and carbon disulfide. The reactions with heavier chalcogens led to the rapid formation of 1:1 dinuclear adducts which were characterized by elemental analysis, ESI-MS measurements, H-1 NMR spectroscopy, and structurally characterized by X-ray diffraction (in the case of reaction products with S-8 (3) and Te (5)). The reaction of 1 with carbon disulfide and elemental sulfur yields the remarkable compound{{2-[(CH3)(2)NCH2](2)C6H4}Sn}(2)(mu(2)-S2C=CS2) (3a). The stability and reactivity of compounds 1-5 were rationalized at DFT/TZ2P level

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

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Volume of the periodical

694

Issue of the periodical within the volume

18

Country of publishing house

CH - SWITZERLAND

Number of pages

4

Pages from-to

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UT code for WoS article

000268265200001

EID of the result in the Scopus database

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