Reactivity of a C,N-Chelated Stannoxane

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F09%3A10001118" target="_blank" >RIV/00216208:11310/09:10001118 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/09:00008302
Result on the web
—
DOI - Digital Object Identifier
—

Result language
angličtina
Original language name
Reactivity of a C,N-Chelated Stannoxane
Original language description
The stannylene {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn (1) did not react with CO2 at room temperature and atmospheric pressure, but its oxidation product {[2-[(CH3)(2)NCH2](2)C6H4](2)Sn-(mu-O)}(2) (2) is very reactive toward CO2 to give the cyclic compound {[2-[(CH3)(2)NCH2](2)C6H4}(2)Sn](2)(mu-O)(mu-CO3) (2b). The product of reaction of 2 with silicon grease is also a cyclic compound with an eight-membered ring, {{{2-[(CH3)(2)NCH2](2)C6H4}(2)Sn}(Me2SiO)}(2) (2c), as the structural characterization revealed (XRD). Triphenylsilanol condensates with 2 to form {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn(OSiPh3)(2) (2b). The reaction of 2 with ethylene glycol gave the cyclic compound {2-[(CH3)(2)-NCH2](2)C6H4}(2)Sn(OCH2CH2O) center dot 1/2(HOCH2CH2OH)(2e).
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2009
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)