Aminostannanes and Asminostannylenes Containing a C,N-chelated Ligand

Result code in IS VaVaI

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Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Aminostannanes and Asminostannylenes Containing a C,N-chelated Ligand

Original language description

Aminotin(II and IV) compounds {[(2,6-i-Pr-C6H3)(H) N]-mu-(Sn)-Cl}(2), {2-[(CH3)(2)NCH2]C6H4}(2)Sn[N(H) (2,6-i-Pr-C6H3)](2) and {2-[(CH3)(2)NCH2]C6H4}Sn[N(2,6-i-Pr-C6H3)(SiMe3)] were prepared by lithium halide elimination from tin halides and corresponding lithium complexes. [(2,6-i-Pr-C6H3)(H) N] Li (1) reacts with one half of molar equivalent of SnCl2 to give {[(2,6-i-Pr-C6H3)(H) N]-mu(Sn)-Cl}(2). The same lithium amide (1) gave with R3SnCl corresponding aminostannanes. Further reactions of these compounds with n-butyllithium gave the starting 1 and tetraorganostannanes. {2-[(CH3)(2)NCH2] C6H4}(2)SnBr2 reacts with two equivalents of 1 to {2-[(CH3)(2)NCH2]C6H4}(2)Sn[N(H)(2,6-i-Pr-C6H3)](2). The dimeric heteroleptic stannylene {[(2,6-i-Pr-C6H3)(SiMe3)N](mu(2)-Cl)Sn}(2) reacts with 2-[(CH3)(2)NCH2] C6H4Li to the monomeric {2-[(CH3)(2)NCH2]C6H4}Sn[N(2,6-i-Pr-C6H3)(SiMe3)].

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

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Volume of the periodical

695

Issue of the periodical within the volume

24

Country of publishing house

CH - SWITZERLAND

Number of pages

7

Pages from-to

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UT code for WoS article

000282677200013

EID of the result in the Scopus database

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