Antimony(III) and bismuth(III) amides containing pendant N-donor groups - a combined experimental and theoretical study

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F15%3A39900600" target="_blank" >RIV/00216275:25310/15:39900600 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c4dt02692f" target="_blank" >http://dx.doi.org/10.1039/c4dt02692f</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4dt02692f" target="_blank" >10.1039/c4dt02692f</a>

Result language
angličtina
Original language name
Antimony(III) and bismuth(III) amides containing pendant N-donor groups - a combined experimental and theoretical study
Original language description
N,N- and N,N,N-chelated antimony(III) and bismuth(III) chlorides L1-3MCl2 1-4 [for L-1: M = Sb (1), for L-2: M = Sb (2) and for L-3: M = Sb (3) and Bi (4)], containing ligands L1-3 derived from the pyrrole ring (where L-1 = C4H3N-2-(CH-N-2',6'-iPr(2)C(6)H(3)), L-2 = C4H2N-2,5-(CH2NMe2)(2), L-3 = C4H2N-2,5-(CH2NC4H8)(2)), were prepared by the treatment of lithium precursors with SbCl3 or BiCl3. Molecular structures of 1-4 were described both in solution (NMR spectroscopy) and in the solid state (single-crystal X-ray diffraction analysis). Structures of 1-4 were also subjected to a density functional theory study.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP207%2F12%2F0223" target="_blank" >GAP207/12/0223: Hybrid ligands for low valent metal centres stabilization/specific activation.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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