Different hydrolytic stabilities of some C,N-chelated germanium alkoxides

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39902110" target="_blank" >RIV/00216275:25310/16:39902110 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.inoche.2016.04.020" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2016.04.020</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.inoche.2016.04.020" target="_blank" >10.1016/j.inoche.2016.04.020</a>

Result language
angličtina
Original language name
Different hydrolytic stabilities of some C,N-chelated germanium alkoxides
Original language description
C,N-intramolecularly coordinated germanium(IV) methoxides Ar3GeOMe (1) and (Ar ')(2)Ge(OMe)(2) (2) [where Ar = [2-(Me2NCH2)C6H4](-), Ar ' = [2-(DipN = CH)C6H4](-), Dip = 2,6-(i-Pr)(2)C6H3] were prepared by the reaction of the lithium precursors ArLi and Ar ' Li with Ge(OMe)(4) in appropriate molar ratio. While the diorganogermanium(IV) compound 2 is air-stable specie, triorganogermanium(IV) compound is surprisingly smoothly hydrolyzed by air-moisture to corresponding triorganogermanol Ar3GeOH (3). Studied compounds were characterized by the help of multinuclear NMR spectroscopy and in the case of 2 and 3 using single-crystal X-ray diffraction analysis.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA13-00289S" target="_blank" >GA13-00289S: Heteroboroxines-A New Class of Boroxine Based Compounds</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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