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A modified vacuum stability test in the study of initiation reactivity of nitramine explosives

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911096" target="_blank" >RIV/00216275:25310/17:39911096 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.tca.2017.08.006" target="_blank" >http://dx.doi.org/10.1016/j.tca.2017.08.006</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.tca.2017.08.006" target="_blank" >10.1016/j.tca.2017.08.006</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    A modified vacuum stability test in the study of initiation reactivity of nitramine explosives

  • Original language description

    The zero-order reaction rates (specific rate constants) of isothermal decomposition at 120 degrees C of plastic bonded explosives (PBXs) in the first six hours of decomposition were measured by means of the Czech vacuum stability test, STABIL. The PBXs were filled by RDX (1,3,5-trinitro-1,3,5-triazinane), beta-HMX (beta-1,3,5,7-tetranitro-1,3,5,7-tetrazocane), BCHMX and epsilon-CL20 (epsilon-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane, epsilon-HNIW) and, in one case, on a mixture of BCHMX and 3-nitro-1,2,4-triazol-5-one (NTO), in a 1:1 wt. ratio. These nitramines were bonded by 9% by wt. of softened polyisobutylene matrix, 13% by wt. of softened polystyrene-butadiene matrix, 18% by wt. of crosslinked hydroxyl-terminated polybutadiene, 12% by wt. of polydimethylsiloxane and by 40% of TNT. The relationships of specific rate constants with experimental detonation velocities, impact and friction sensitivities of these PBXs are shown and discussed. It is postulated that this approach provides results which are applicable to studies of initiation reactivity of energetic materials and which are fully comparable with those of other methods of investigation in this area.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Thermochimica Acta

  • ISSN

    0040-6031

  • e-ISSN

  • Volume of the periodical

    656

  • Issue of the periodical within the volume

    October

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    9

  • Pages from-to

    16-24

  • UT code for WoS article

    000414816900003

  • EID of the result in the Scopus database