A modified vacuum stability test in the study of initiation reactivity of nitramine explosives
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911096" target="_blank" >RIV/00216275:25310/17:39911096 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.tca.2017.08.006" target="_blank" >http://dx.doi.org/10.1016/j.tca.2017.08.006</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tca.2017.08.006" target="_blank" >10.1016/j.tca.2017.08.006</a>
Alternative languages
Result language
angličtina
Original language name
A modified vacuum stability test in the study of initiation reactivity of nitramine explosives
Original language description
The zero-order reaction rates (specific rate constants) of isothermal decomposition at 120 degrees C of plastic bonded explosives (PBXs) in the first six hours of decomposition were measured by means of the Czech vacuum stability test, STABIL. The PBXs were filled by RDX (1,3,5-trinitro-1,3,5-triazinane), beta-HMX (beta-1,3,5,7-tetranitro-1,3,5,7-tetrazocane), BCHMX and epsilon-CL20 (epsilon-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane, epsilon-HNIW) and, in one case, on a mixture of BCHMX and 3-nitro-1,2,4-triazol-5-one (NTO), in a 1:1 wt. ratio. These nitramines were bonded by 9% by wt. of softened polyisobutylene matrix, 13% by wt. of softened polystyrene-butadiene matrix, 18% by wt. of crosslinked hydroxyl-terminated polybutadiene, 12% by wt. of polydimethylsiloxane and by 40% of TNT. The relationships of specific rate constants with experimental detonation velocities, impact and friction sensitivities of these PBXs are shown and discussed. It is postulated that this approach provides results which are applicable to studies of initiation reactivity of energetic materials and which are fully comparable with those of other methods of investigation in this area.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Thermochimica Acta
ISSN
0040-6031
e-ISSN
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Volume of the periodical
656
Issue of the periodical within the volume
October
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
9
Pages from-to
16-24
UT code for WoS article
000414816900003
EID of the result in the Scopus database
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