Quest for stable or masked pnictinidenes: Emerging and exciting class of group 15 compounds

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911700" target="_blank" >RIV/00216275:25310/17:39911700 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Quest for stable or masked pnictinidenes: Emerging and exciting class of group 15 compounds

Original language description

The chemistry of low-valent main group compounds represents one of the most exciting and quickly developing areas in the field of organometallic and organoelement chemistry. In this context, this chapter is focused on the chemistry of monomeric pnictogen(I) compounds (R-E) (where E = P, As, Sb and Bi), that are known as pnictinidenes. These compounds are elusive and rather reactive substances. It was not possible to isolate them at ambient conditions for a long time except as complexes with various transition metals. This work summarizes most important results achieved during the quest for their synthesis and characterization as transition metal free species. Their coordination by Lewis bases represents the most frequently used way how to fulfill this challenging task, although unique non-coordinated phosphinidenes emerged recently as well. The structure of such base-stabilized pnictinidenes is more or less perturbed in comparison with their elusive parent non-coordinated originals. Nevertheless, their appearance as relatively easy-handling species opened a way for their future investigation and application as model-compounds for &quot;true&quot; pnictinidenes.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10402 - Inorganic and nuclear chemistry

Project

<a href="/en/project/GA15-06609S" target="_blank" >GA15-06609S: Stibinidenes and Bismuthinidenes – A New Class of Ligands for Transition Metals</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2017

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Coordination Chemistry Reviews

ISSN

0010-8545

e-ISSN

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Volume of the periodical

353

Issue of the periodical within the volume

December

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

17

Pages from-to

142-158

UT code for WoS article

000417551600004

EID of the result in the Scopus database

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