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Promising new insensitive cocrystal

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39912716" target="_blank" >RIV/00216275:25310/18:39912716 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Promising new insensitive cocrystal

  • Original language description

    A novel energetic co-crystal based on 1,4-dinitro-1,4-diazabutane (EDNA) and 1,5-diaminotetrazole (DAT) in a 1:2 molar ratio was synthesized. The formation of the cocrystal was monitored by Scanning electron microscope (SEM), powder X-ray diffraction (PXRD) and Raman spectroscopy. Sensitivity to impact was measured and 50% probability of initiation was 9.73 J for the cocrystal and 15.4 J for the EDNA. In addition, the detonation characteristics were predicted by EXPLO5 Code. The detonation velocity (D) and the detonation pressure (P) of the cocrystal are 8254.5 m s-1 and 26.7 GPa respectively. The obtained cocrystal possesses a promising future for expanding the reuse of EDNA in antitank ammunition after overcome the acidity problem with the explosive in addition, the higher nitrogen content and acceptable sensitivity to external stimuli.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    20501 - Materials engineering

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Proceedings of the 21st Seminar on New Trends in Research of Energetic Materials

  • ISBN

    978-80-7560-136-0

  • ISSN

  • e-ISSN

    neuvedeno

  • Number of pages

    9

  • Pages from-to

    678-686

  • Publisher name

    Univerzita Pardubice

  • Place of publication

    Pardubice

  • Event location

    Pardubice

  • Event date

    Apr 18, 2018

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article