Stabilization of two coordinate tetrylene by borylamide ligand

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39913488" target="_blank" >RIV/00216275:25310/18:39913488 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jorganchem.2018.07.020" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2018.07.020</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2018.07.020" target="_blank" >10.1016/j.jorganchem.2018.07.020</a>

Result language
angličtina
Original language name
Stabilization of two coordinate tetrylene by borylamide ligand
Original language description
Here we report the synthesis of aminoborane HN(BCy2) (C6H3-2,6-Me-2) (1) (Cy = cyclohexyl), that was successfully deprotonated and its lithium salt {LiN(BCy2) (C6H3-2,6-Me-2)}(2) (2) has been characterised. The borylamide ligand -N(BCy2) (C6H3-2,6-Me-2) was used for the preparation of N -> Sn coordinated stannylene [2,6-(Me2NCH2)(2)C6H3]Sn [N(BCy2) (C6H3-2,6-Me-2)] (3) and two coordinate tetrylenes {E [N(BCy2) (C6H3-2,6-Me-2)](2)} (E = Sn (4), Pb (5)). Experimental and theoretical studies suggested sigma character of E-N bonds without additional N(p)-> E(p) donation as the result of the preference of N(p)-> B(p) donation in 4 and 5. DFT studies on 4 and 5 also reveal theirs HOMO to exhibit E lone pair character and theirs LUMO to include p-orbital character located on metal atoms E. (C) 2018 Elsevier B.V. All rights reserved.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA18-03823S" target="_blank" >GA18-03823S: Advanced methods of fabrication of chalcogenide thin films and their modifications</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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