Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898823" target="_blank" >RIV/00216275:25310/14:39898823 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om500698k" target="_blank" >http://dx.doi.org/10.1021/om500698k</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om500698k" target="_blank" >10.1021/om500698k</a>

Result language
angličtina
Original language name
Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes
Original language description
The synthesis of the C,N-chelated homoleptic organotetrylenes (L1)2E (1, E = Sn; 2, E = Pb) and of the tungsten pentacarbonyl complex (L1)2SnW(CO)5 (3), containing the sterically demanding C,N-chelating ligand L1 (L1 = [2-{(C6H3-2,6-Pri2)N?CH}C6H4]?) isreported. In contrast, the use of the C,N-chelated ligand L2 (L2 = [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)]?) provided either the homoleptic stannylene (L2)2Sn (4) or the C,N-chelated chlorostannylene (L2)SnCl (5). All attempts to convert the latter intothe corresponding ditin compound [L2Sn]2 failed, however, and resulted in the isolation of 4 and elemental tin. These attempts also provided the unprecedented complex [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)][2-{(C6H3-2,6-Pri2)NHCH(Me)}C6H2(OCH2O)]Sn (6).
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA13-00289S" target="_blank" >GA13-00289S: Heteroboroxines-A New Class of Boroxine Based Compounds</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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