Spontaneous Hydrosilylation of Substituted C=N Imines
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39914801" target="_blank" >RIV/00216275:25310/19:39914801 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.201900516" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.201900516</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201900516" target="_blank" >10.1002/ejic.201900516</a>
Alternative languages
Result language
angličtina
Original language name
Spontaneous Hydrosilylation of Substituted C=N Imines
Original language description
4-Methoxy and 2,4-di-tBu substituted C,N-chelating ligands 2-[(2,6-iPr(2)-C6H3)N=CH]-4-MeO-C6H3}(-) and {2-[(2,6-iPr(2)-C6H3)N=CH]-4,6-tBu(2)-C6H3}(-) and also {2-[(2,6-Me-2-C6H3)N=C(Me)]-C6H4}(-) and {2-[(2,6-iPr(2)-C6H3)N=C(Me)]-5,6-OCH2O-C6H2}(-) containing Me substituted imine group were used for the preparation of intramolecularly coordinated organohydridosilanes L1-4PhnSiH4-n and (LSiHCl2)-Si-1. The spontaneous hydrosilylation reaction occurs very quickly in L1-4PhnSiH4-n and hydrosilylated products are formed. In contrast, the isolation of (LSiHCl2)-Si-1 allows us to study kinetics of the hydrosilylation.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
Neuveden
Issue of the periodical within the volume
28
Country of publishing house
DE - GERMANY
Number of pages
8
Pages from-to
3335-3342
UT code for WoS article
000477907900010
EID of the result in the Scopus database
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