Reactivity of a NSn Coordinated Distannyne: Reduction and Hydrogen Abstraction
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39913490" target="_blank" >RIV/00216275:25310/18:39913490 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201800370" target="_blank" >http://dx.doi.org/10.1002/ejic.201800370</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201800370" target="_blank" >10.1002/ejic.201800370</a>
Alternative languages
Result language
angličtina
Original language name
Reactivity of a NSn Coordinated Distannyne: Reduction and Hydrogen Abstraction
Original language description
The reduction ability of a NSn coordinated distannyne {LSn}(2), where L is [C6H3-2,6-(Me2NCH2)(2)](-) is tested towards organic molecules ethylene and cyclooctatetraene. These reactions provide the compound [{LSn}(3)SnH] (2), as the result of a hydride abstraction. DFT calculations suggest that compound 2 can be interpreted as highly covalently bonded {HSnI} and {((SnL)-L-I)(3)} fragments. While the reduction of the C=C bond is not observed in the reaction of 1 with organic molecules, the reducing ability of 1 is observed in the reaction with inorganic SnO. Complex 1 is able to reduce SnO and the organotin(II) oxide {LSn}(2)O (3) is obtained. Moreover, compound 3 is able to coordinate an excess of SnO to yield the organotin(II)-tin(II)-oxo cluster L4Sn10O8 (4).
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/LM2015082" target="_blank" >LM2015082: Center of Materials and Nanotechnologies</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
Neuveden
Issue of the periodical within the volume
19
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
2038-2044
UT code for WoS article
000433496400013
EID of the result in the Scopus database
2-s2.0-85047659077