From Monomeric Tin(II) Hydride to Nonsymmetric Distannyne
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39915098" target="_blank" >RIV/00216275:25310/19:39915098 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.organomet.9b00215" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.organomet.9b00215</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.organomet.9b00215" target="_blank" >10.1021/acs.organomet.9b00215</a>
Alternative languages
Result language
angličtina
Original language name
From Monomeric Tin(II) Hydride to Nonsymmetric Distannyne
Original language description
The monomeric tin(II) hydride L-2(H)Sn center dot W(CO)(5) (2), where L-2 is 2-Et2NCH2-4,6-tBu(2)-C6H2, was easily transformed to the nonsymmetrical distannyne (LSnSnL2)-Sn-1 center dot W(CO)(5) (4), where L-1 is 2,6-(Me2NCH2)(2)C6H3, by an amine elimination reaction with the tin(II) amide (LSnNEt2)-Sn-1 (3), without additional initiators such as N-bases or NHC carbenes. DFT calculations showed that the substitution of an SnH atom by an SnL1 fragment strongly affects the (LSnW)-Sn-2(CO)(5) fragment, which accumulates a larger amount of electron density.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA18-03823S" target="_blank" >GA18-03823S: Advanced methods of fabrication of chalcogenide thin films and their modifications</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
—
Volume of the periodical
38
Issue of the periodical within the volume
12
Country of publishing house
US - UNITED STATES
Number of pages
5
Pages from-to
2403-2407
UT code for WoS article
000473116400001
EID of the result in the Scopus database
—