N-Coordinated Tin(II) Trifluoromethanesulfonates and Their Reactions with Transition Metal Carbonyls

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F15%3A39900607" target="_blank" >RIV/00216275:25310/15:39900607 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/acs.inorgchem.5b00678" target="_blank" >http://dx.doi.org/10.1021/acs.inorgchem.5b00678</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.5b00678" target="_blank" >10.1021/acs.inorgchem.5b00678</a>

Result language
angličtina
Original language name
N-Coordinated Tin(II) Trifluoromethanesulfonates and Their Reactions with Transition Metal Carbonyls
Original language description
The syntheses of the compounds [(LSnCl)-Sn-1][M-(CO)(5)(SnCl3)] (3, M = W; 4, M = Cr), [(LSnCl)-Sn-1]OTf (5), [(LSnCl)-Sn-1][W(CO)(5)(SnCl2OTf)] (6), [(LSnOTf)-Sn-1][OTf] (7), and [(LSn)-Sn-2(OTf)(2)] (8) with L-1 = {2,6-[(CH3)C=N(C6H3-2,6-Pr-i(2))(2)]C5H3N} (DIMPY) and L-2 = {2-[(CH3)C=N-(C6H3-2,6-Pr-i(2))]-6-(CH3O)}C5H3N) is reported. The compounds were characterized by elemental analyses, H-1, C-13, F-19, and Sn-119 NMR spectroscopy, electrospray ionization mass spectrometry, and single-crystal X-raydiffraction analyses (3 center dot 1.5C(7)H(8), 5 center dot CH2Cl2, 7 center dot C7H8, 8). For compounds 7 and 8, the experimental work is accompanied by density functional theory calculations.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA15-07091S" target="_blank" >GA15-07091S: Uncatalyzed Hydrosilylations Induced by N→Si Coordination</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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