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Thermoelectric Properties of FeSb2Te Based Ternary Skutterudites with Mo Nanoinclusions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39915214" target="_blank" >RIV/00216275:25310/19:39915214 - isvavai.cz</a>

  • Result on the web

    <a href="http://www.materialstoday.com/proceedings" target="_blank" >http://www.materialstoday.com/proceedings</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.matpr.2019.02.058" target="_blank" >10.1016/j.matpr.2019.02.058</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thermoelectric Properties of FeSb2Te Based Ternary Skutterudites with Mo Nanoinclusions

  • Original language description

    Polycrystalline samples of FeSb2Te ternary skutterudite based compounds were prepared by the powder metallurgy method. The influence of additions of Mo nanoparticles into host-matrix compound (FeSb2Te) was investigated. Wet blending route (ultrasonication/rotavapor) was used to obtain homogeneous dispersion of the host-matrix compound with Mo nanoparticles. The nanocomposite powders FeSb2Te+x vol.% Mo (x=0, 2, 4, 6) were hot-pressed for 1hr at 500°C/70 MPa. The prepared p-type samples were characterized by measurements of their electrical conductivity, Seebeck coefficient, and thermal conductivity. SEM and EDX results revealed Mo nanoparticles mainly inside of intergrain space of the host-matrix material. Strikingly, Mo does not react with the matrix material. The presence of the Mo nanoparticles in the intergrain space appears to reduce phonon mean free path resulting in a reduction of the thermal conductivity of the studied nanocomposite materials. The extra scattering of phonons on the embedded Mo nanoparticles is responsible for about 20% increase of ZT at some of the nanocomposite samples.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    <a href="/en/project/GA16-07711S" target="_blank" >GA16-07711S: A systematic study of Schottky barrier height effect on energy filtering of electrons in thermoelectric nanocomposites.</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Materials Today : Proceedings

  • ISBN

  • ISSN

    2214-7853

  • e-ISSN

  • Number of pages

    8

  • Pages from-to

    592-599

  • Publisher name

    Elsevier

  • Place of publication

    Kidlington

  • Event location

    Padova

  • Event date

    Sep 25, 2017

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article

    000468329300012