Bis(silylene)-Stabilized Monovalent Nitrogen Complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F20%3A39916639" target="_blank" >RIV/00216275:25310/20:39916639 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202011598" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202011598</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202011598" target="_blank" >10.1002/anie.202011598</a>
Alternative languages
Result language
angličtina
Original language name
Bis(silylene)-Stabilized Monovalent Nitrogen Complexes
Original language description
The first series of bis(silylene)-stabilized nitrogen(I) compounds is described. Starting from the 1,2-bis(N-heterocyclic silylenyl) 1,2-dicarba-closo-dedocaborane(12) scaffold1, [1,2-(LSi)(2)C2B10H10; L=PhC((NBu)-Bu-t)(2)], reaction with adamantyl azide (AdN(3)) affords the terminal N-mu(2)-bridged zwitterionic carborane-1,2-bis(silylium) AdN(3)adduct2with an open-cage dianionic nido-C(2)B(10)cluster core. Remarkably, upon one-electron reduction of2with C8K and liberation of N(2)and adamantane, the two silylene subunits are regenerated to furnish the isolable bis(silylene)-stabilized N(I)complex as an anion of3with the nido-C(2)B(10)cluster cage. On the other hand, one-electron oxidation of2with silver(I) yields the monocationic bis(silylene) N(I)complex4with the closo-C(2)B(10)cluster core. Moreover, the corresponding neutral N(I)radical complex5results from single-electron transfer from3to4.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie (International Edition)
ISSN
1433-7851
e-ISSN
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Volume of the periodical
59
Issue of the periodical within the volume
49
Country of publishing house
DE - GERMANY
Number of pages
5
Pages from-to
22043-22047
UT code for WoS article
000573171700001
EID of the result in the Scopus database
2-s2.0-85091613883