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Bis(silylene)-Stabilized Monovalent Nitrogen Complexes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F20%3A39916639" target="_blank" >RIV/00216275:25310/20:39916639 - isvavai.cz</a>

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202011598" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202011598</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/anie.202011598" target="_blank" >10.1002/anie.202011598</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Bis(silylene)-Stabilized Monovalent Nitrogen Complexes

  • Original language description

    The first series of bis(silylene)-stabilized nitrogen(I) compounds is described. Starting from the 1,2-bis(N-heterocyclic silylenyl) 1,2-dicarba-closo-dedocaborane(12) scaffold1, [1,2-(LSi)(2)C2B10H10; L=PhC((NBu)-Bu-t)(2)], reaction with adamantyl azide (AdN(3)) affords the terminal N-mu(2)-bridged zwitterionic carborane-1,2-bis(silylium) AdN(3)adduct2with an open-cage dianionic nido-C(2)B(10)cluster core. Remarkably, upon one-electron reduction of2with C8K and liberation of N(2)and adamantane, the two silylene subunits are regenerated to furnish the isolable bis(silylene)-stabilized N(I)complex as an anion of3with the nido-C(2)B(10)cluster cage. On the other hand, one-electron oxidation of2with silver(I) yields the monocationic bis(silylene) N(I)complex4with the closo-C(2)B(10)cluster core. Moreover, the corresponding neutral N(I)radical complex5results from single-electron transfer from3to4.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Angewandte Chemie (International Edition)

  • ISSN

    1433-7851

  • e-ISSN

  • Volume of the periodical

    59

  • Issue of the periodical within the volume

    49

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    5

  • Pages from-to

    22043-22047

  • UT code for WoS article

    000573171700001

  • EID of the result in the Scopus database

    2-s2.0-85091613883