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Interaction of heteroboranes with biomolecules, Part 2: The effect of various metal vertices and exo-substitutions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F07%3A00081637" target="_blank" >RIV/61388963:_____/07:00081637 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Interaction of heteroboranes with biomolecules, Part 2: The effect of various metal vertices and exo-substitutions

  • Original language description

    In this study, we investigate the effect of various metal vertices and exo-substitutions on several series of heteroboranes, including 11-vertex carborane cages [nido-7,8-C2B9Hn]n-13 (n=11,12,13), closo-1-SB11H11, closo-1-NB11H12, metal bis(dicarbollides) [3,3?-M (1,2-C2B9H11)2]n (M/n = Fe/2-, Co/1-, Ni/0) and fluoro (F), amino (NH2) and hydroxo (OH) derivatives of the metal bis(dicarbolides). Besides the properties of isolated systems (geometries, electronic properties and hydration), we study their interactions with a tetrapeptide, which models their biomolecular partner.

  • Czech name

    Interakce heteroboranů s biomolekulamy, Část 2: Efekt zám?ny vrcholu and exo-substitucí

  • Czech description

    V tomto clanku se zabývame vlivem různych vrcholů a exo-substitucí v nekolika seriich heteroboranů, včetne 11-vcholových carboránových klecí [nido-7,8-C2B9Hn]n-13 (n=11,12,13), closo-1-SB11H11, closo-1-NB11H12, metal bis(dicarbollides) [3,3?-M (1,2-C2B9H11)2]n (M/n = Fe/2-, Co/1-, Ni/0) a fluoro (F), amino (NH2) and hydroxo (OH) derivatů metal bis(dicarbolidů). Vedle vlastností isolovaných systemů (geometrie, electronové vlastnosti a hydratace), jsme se zabývali jejich interakcemi s tetrapeptidem, kterým modelujeme jejich biomolecularního partnera.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2007

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Chemistry Chemical Physics

  • ISSN

    1463-9076

  • e-ISSN

  • Volume of the periodical

    9

  • Issue of the periodical within the volume

    17

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    9

  • Pages from-to

    2085-2093

  • UT code for WoS article

  • EID of the result in the Scopus database