Transition-Metal Capping to Suppress Back-Donation to Enhance Donor Ability
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F20%3A39916649" target="_blank" >RIV/00216275:25310/20:39916649 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.organomet.0c00534" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.organomet.0c00534</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.organomet.0c00534" target="_blank" >10.1021/acs.organomet.0c00534</a>
Alternative languages
Result language
angličtina
Original language name
Transition-Metal Capping to Suppress Back-Donation to Enhance Donor Ability
Original language description
The design of strong donor ligands has been one of the crucial tasks in the development of ligands for transition-metal complexes. One effective strategy is suppression of back-donation from a metal to a ligand by electron donation from adjacent main-group atoms bearing lone-pair electrons. We now report another method for suppression of back-donation: capping an accepting orbital by coordination of a transition metal. A lone pair on the triple-decker ruthenocene-type stannole complex can coordinate an Mo(CO)5 moiety. In the resulting complex, back-donation from a Mo to an Sn moiety is effectively suppressed because of the occupation of a potentially electron-accepting 5p orbital on the Sn atom by coordination of the Ru moieties. The triple-decker ruthenocene-type stannole complex can also coordinate an Ag(I) atom to form a 1:2 complex, where two bulky ligands are oriented in a perpendicular fashion.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
—
Volume of the periodical
39
Issue of the periodical within the volume
23
Country of publishing house
US - UNITED STATES
Number of pages
5
Pages from-to
"4191–4194"
UT code for WoS article
000599997800014
EID of the result in the Scopus database
2-s2.0-85094603012