Low Valent N-Coordinated Cations and Dications of Heavier Group 14 Elements: Lewis Acids or Bases?
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F23%3A39920648" target="_blank" >RIV/00216275:25310/23:39920648 - isvavai.cz</a>
Result on the web
<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202300505" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202300505</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.202300505" target="_blank" >10.1002/ejic.202300505</a>
Alternative languages
Result language
angličtina
Original language name
Low Valent N-Coordinated Cations and Dications of Heavier Group 14 Elements: Lewis Acids or Bases?
Original language description
Low-valent N-coordinated cations and dications of heavier group 14 elements are of great interest in recent years. Their unique electronic structure gives them an ambiphilic character, as they contain both a lone electron pair and an empty p-orbital on the central metal atom. Thanks to their nucleophilic character, these compounds can act as ligands in transition metal chemistry, and conversely, their electrophilic character allows them to interact with a wide range of organic substrates and thus replace catalysts based on transition metal complexes in many chemical transformations. The aim of this article is to summarize the synthesis of N-coordinated ionic compounds of heavier group 14 elements with their subsequent reactivity towards various nucleophiles and electrophiles.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA23-06548S" target="_blank" >GA23-06548S: Superhydrophobic materials based on heteroboroxines</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
1099-0682
Volume of the periodical
26
Issue of the periodical within the volume
34
Country of publishing house
DE - GERMANY
Number of pages
13
Pages from-to
"e202300505"
UT code for WoS article
001085611500001
EID of the result in the Scopus database
2-s2.0-85174242333