Distinctly different reactivity of bis(silylenyl)-versus phosphanyl-silylenyl-substituted o-dicarborane towards O-2, N2O and CO2
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F21%3A39918332" target="_blank" >RIV/00216275:25310/21:39918332 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2021/CC/D1CC01939B" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/CC/D1CC01939B</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1cc01939b" target="_blank" >10.1039/d1cc01939b</a>
Alternative languages
Result language
angličtina
Original language name
Distinctly different reactivity of bis(silylenyl)-versus phosphanyl-silylenyl-substituted o-dicarborane towards O-2, N2O and CO2
Original language description
In stark contrast to the reactivity of the bis-silylenyl dicarborane CB-Si-2 (1) [CB = ortho-C,C'-C2B10H10, Si = PhC(tBuN)(2)Si] towards O-2, N2O, and CO2, yielding the same dioxygenation product CB-Si2O2 (2) with a four-membered 1,3,2,4-disiladioxetane ring, the activation of the latter small molecules with the phosphanyl-silylenyl-functionalised CB-SiP (3) {PQP[N(tBu)CH2](2)} affords with O-2 the CB-Si(=O)P(=O) silanone-phosphine oxide (4), with N2O the CB-Si(=O)P silanone-phosphine (5), and with CO2 the CB-Si(O2C=O)P silicon carbonate-phosphine (6) and CB-C(=O)OSiOP ester (7), respectively.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Communications
ISSN
1359-7345
e-ISSN
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Volume of the periodical
57
Issue of the periodical within the volume
48
Country of publishing house
GB - UNITED KINGDOM
Number of pages
4
Pages from-to
5965-5968
UT code for WoS article
000653080700001
EID of the result in the Scopus database
2-s2.0-85107942201