Thiaborane Icosahedral Barrier Increased by the Functionalization of all Terminal Hydrogens in closo-1-SB11H11
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F21%3A39918347" target="_blank" >RIV/00216275:25310/21:39918347 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/21:00543366 RIV/61388963:_____/21:00543366
Result on the web
<a href="https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c00796" target="_blank" >https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c00796</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.1c00796" target="_blank" >10.1021/acs.inorgchem.1c00796</a>
Alternative languages
Result language
angličtina
Original language name
Thiaborane Icosahedral Barrier Increased by the Functionalization of all Terminal Hydrogens in closo-1-SB11H11
Original language description
The electrophilic substitution of icosahedral closo-1-SB11H11 with methyl iodide has resulted in two B-functionalized thiaboranes, 7,12-I-2-2,3,4,5,6,8,9,10,11-(CH3)(9)-1-closo-SB11 and 7,8,12-I-3-2,3,4,5,6,9,10,11-(CH3)(8)-closo-1-SB11, with the former being significantly predominant. These two icosahedral thiaboranes are the first cases of polysubstituted polyhedral boron clusters with another vertex that differs from B and C. Such polyfunctionalizations have increased the earlier observed thiaborane icosahedral barrier, not exhibiting any reactivity toward bases, unlike the parent thiaborane. The search for methylation pathways has revealed that the complete B-11-methylation is impossible, like in the case of decaborane(14), where this seems to be a result of the positively charged upper parts of these two molecules.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA19-17156S" target="_blank" >GA19-17156S: Chemistry of globular shaped hydrocarbons with boron–cage scaffolding inside the methylated sheath</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
60
Issue of the periodical within the volume
12
Country of publishing house
US - UNITED STATES
Number of pages
4
Pages from-to
8428-8431
UT code for WoS article
000664576700011
EID of the result in the Scopus database
2-s2.0-85108624925