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Thiaborane Icosahedral Barrier Increased by the Functionalization of all Terminal Hydrogens in closo-1-SB11H11

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F21%3A39918347" target="_blank" >RIV/00216275:25310/21:39918347 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388980:_____/21:00543366 RIV/61388963:_____/21:00543366

  • Result on the web

    <a href="https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c00796" target="_blank" >https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c00796</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acs.inorgchem.1c00796" target="_blank" >10.1021/acs.inorgchem.1c00796</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thiaborane Icosahedral Barrier Increased by the Functionalization of all Terminal Hydrogens in closo-1-SB11H11

  • Original language description

    The electrophilic substitution of icosahedral closo-1-SB11H11 with methyl iodide has resulted in two B-functionalized thiaboranes, 7,12-I-2-2,3,4,5,6,8,9,10,11-(CH3)(9)-1-closo-SB11 and 7,8,12-I-3-2,3,4,5,6,9,10,11-(CH3)(8)-closo-1-SB11, with the former being significantly predominant. These two icosahedral thiaboranes are the first cases of polysubstituted polyhedral boron clusters with another vertex that differs from B and C. Such polyfunctionalizations have increased the earlier observed thiaborane icosahedral barrier, not exhibiting any reactivity toward bases, unlike the parent thiaborane. The search for methylation pathways has revealed that the complete B-11-methylation is impossible, like in the case of decaborane(14), where this seems to be a result of the positively charged upper parts of these two molecules.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    <a href="/en/project/GA19-17156S" target="_blank" >GA19-17156S: Chemistry of globular shaped hydrocarbons with boron–cage scaffolding inside the methylated sheath</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Inorganic Chemistry

  • ISSN

    0020-1669

  • e-ISSN

  • Volume of the periodical

    60

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    4

  • Pages from-to

    8428-8431

  • UT code for WoS article

    000664576700011

  • EID of the result in the Scopus database

    2-s2.0-85108624925