Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F05%3APU50170" target="_blank" >RIV/00216305:26310/05:PU50170 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Polymerization of hex-1-ene initiated by diimine complexes of nickel and palladium
Original language description
Hex-1-ene polymerization in the presence of palladium and nickel diimine complexes was examined. Influence of the chain walking mechanism on the polymerization rate and polymer microstructure was investigated. The kinetic study of the most active Ni system was performed with impact on influence of monomer concentration on polymerization rate and polyolefin microstructure. Catalyst efficiency was estimated. Polyhex-1-ene microstructure was investigated in detail by 1H and 13C NMR analysis.
Czech name
Polymerace hex-1-enu iniciovaná diiminovými komplexy niklu a paladia
Czech description
Byla studován vliv koncentrace monomeru na rychlost propagace a rozsah přenosových reakcí při polymerci hex-1-enu na diiminových katalyzátorech Ni a Pd. Pomocí NMR byla studována mikrostruktura polyhexenu daná rovnováhou mezi propagační a izomerační reakcí.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Project
<a href="/en/project/OC%20D17.10" target="_blank" >OC D17.10: Synthesis and characterization of polyolefinic macromonomers</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2005
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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