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Impact of Zn salts on hydration, compressive strength, microstructure, leachability and toxicity of ordinary Portland cement

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F14%3APU112781" target="_blank" >RIV/00216305:26310/14:PU112781 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Impact of Zn salts on hydration, compressive strength, microstructure, leachability and toxicity of ordinary Portland cement

  • Original language description

    Ordinary Portland cement (OPC) has been used to solidify of hazardous waste for about 25 years and the effect of waste components on the hydraulic activity is an interesting object for the research. The possible increase of zinc incorporation present insecondary raw materials may lead to changes in behavior of pastes made from OPC. In this study zinc nitrate, chloride and oxide were added to Portland cement. The concentrations of 0.05, 0.1, 0.5 and 1.0 weight percent of zinc in cement were tested. After 1, 7, 28 and 90 days were measured the compressive and flexural strengths. The addition of salts of zinc modifies resulted compressive strength in various ways. The early compressive strength (1 day) decreases in comparison with the reference sample. This difference is probably due to a delay in tricalcium silicate hydration as shown by isothermal and isoperibolic calorimetry. As shown by scanning electron microscopy and X-ray diffraction, zinc is predominantly absorbed in CaZn2(OH)6.2

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů