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Preparation of poly(lactic acid) grafted with itaconic anhydride via radical grafting in melt

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F15%3APU116832" target="_blank" >RIV/00216305:26310/15:PU116832 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Preparation of poly(lactic acid) grafted with itaconic anhydride via radical grafting in melt

  • Original language description

    Proposed study deals with functionalization of poly(lactic acid) (PLA) with itaconic anhydride (IAH) via radical grafting in melt. Reaction was initiated by 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane (L101). Residence time was 6 min and the reaction temperature of 187.4 °C was calculated according to Arrhenius equation. At these reaction conditions L101 is completely decomposed and degradation of PLA is limited. Structure of thus prepared PLA-g-IAH and grafting yield depend on several key parameters such as temperature, IAH/L101 ratio and reaction time.

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů