Capillary gap flow cell as capillary-end electrochemical detector in flow-based analysis

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F19%3APU131844" target="_blank" >RIV/00216305:26620/19:PU131844 - isvavai.cz</a>

Alternative codes found

RIV/62156489:43210/19:43915460

Result on the web

<a href="http://dx.doi.org/10.1016/j.electacta.2019.02.026" target="_blank" >http://dx.doi.org/10.1016/j.electacta.2019.02.026</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.electacta.2019.02.026" target="_blank" >10.1016/j.electacta.2019.02.026</a>

Result language

angličtina

Original language name

Capillary gap flow cell as capillary-end electrochemical detector in flow-based analysis

Original language description

A gap flow cell (gap-FC) as a capillary-end electrochemical (EC) detector, incorporating exchangeable screen-printed electrodes, that facilitates adjustment of the gap distance between the capillary outlet and working electrode down to 30 um was investigated. The analytical performance of the gap-FC was assessed in terms of detector response (current), the efficiency of EC conversion of ferrocyanide, and effective cell volume, as a function of flow rate and gap distance, within a range of 0.1-200 mu L min(-1) and 30-100 mu m, respectively. As a result, an efficiency of EC conversion within the range of similar to 1.5-11% (similar to 3-16 times higher than wall-jet FC), at an effective cell volume of similar to 30-75 nL, was achieved. The gap-FC was applied as a liquid chromatography EC detector, coupled with standard and capillary format liquid chromatographs, where the analytical performance of gap-FC was compared with that of a UV detector. With the standard LC, the sensitivity for ascorbic acid, 2,3-dihydroxybenzoic acid and pyrocatechol, was greater than with the UV detector, with limits of detection (LODs) one order of magnitude lower for the gap-FC (0.10 mu M, 0.09 mu M, 0.19 mu M, respectively, RSD 1.35-3.8%, n = 9, linearity r(2) similar to 0.99 for concentration range 1-100 mu M). LODs of test electroactive solutes using the gap-FC were similar to 2 times lower than LODs reported in existing literature using standard EC detectors, including wall-jet and thin-layer FCs.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2019

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Electrochimica Acta

ISSN

0013-4686

e-ISSN

1873-3859

Volume of the periodical

303

Issue of the periodical within the volume

1

Country of publishing house

GB - UNITED KINGDOM

Number of pages

9

Pages from-to

85-93

UT code for WoS article

000461014900010

EID of the result in the Scopus database

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