A variable-temperature Q- and X-band EPR study of spin-crossover iron(III) Schiff base complex
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F20%3APU140068" target="_blank" >RIV/00216305:26620/20:PU140068 - isvavai.cz</a>
Result on the web
<a href="https://link.springer.com/article/10.1007/s11696-019-00781-2" target="_blank" >https://link.springer.com/article/10.1007/s11696-019-00781-2</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11696-019-00781-2" target="_blank" >10.1007/s11696-019-00781-2</a>
Alternative languages
Result language
angličtina
Original language name
A variable-temperature Q- and X-band EPR study of spin-crossover iron(III) Schiff base complex
Original language description
The mononuclear iron(III) Schiff base complex was analysed by EPR spectroscopy. The first derivative Q- and X-band EPR spectra of spin-crossover iron(III) complex exhibit the presence of the high spin (S = 5/2) and low spin (S = 1/2) iron(III) state. The variable-temperature EPR measurement confirmed a gradual spin-crossover transition (S = 5/2 <-> S = 1/2). The possible hysteresis in the thermally induced spin-crossover effect was not detected. The EPR data are in agreement with observed trends in the magnetic measurements reported previously. Note that the EPR studies of this complex have not been performed before. It is obvious that EPR spectroscopy is a powerful method for investigation of the spin-crossover transition and their temperature evolution in the iron(III) complexes.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Papers
ISSN
0366-6352
e-ISSN
1336-9075
Volume of the periodical
74
Issue of the periodical within the volume
11
Country of publishing house
SK - SLOVAKIA
Number of pages
10
Pages from-to
3683-3692
UT code for WoS article
000563078800003
EID of the result in the Scopus database
2-s2.0-85081349495