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Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F11%3A10222341" target="_blank" >RIV/61989592:15310/11:10222341 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Spin crossover behavior of a one-dimensional polymeric-chain compound {[Fe(abpt)2(u-Ni(CN)4)].xH2O}n (x = 0.5 -0): Synthesis, spectral, thermal and magnetic properties

  • Original language description

    A one-dimensional polymeric-chain iron(II)-nickel(II) cyanido-bridged complex of the composition{[Fe(abpt)2(u-Ni(CN)4)].0.5H2O}n (1.0.5H2O), where abpt = 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole, was prepared and characterized by elemental and thermalanalyses, FTIR and 57Fe Mössbauer spectroscopies,and magnetic measurements. The incomplete spin crossover phenomenon was observed with approximately 12% of the frozen high-spin fraction at low temperatures and with the spin transition critical temperature above room temperature.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Inorganica Chimica Acta

  • ISSN

    0020-1693

  • e-ISSN

  • Volume of the periodical

    365

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    4

  • Pages from-to

    458-461

  • UT code for WoS article

    000285624200068

  • EID of the result in the Scopus database