Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F11%3A33116857" target="_blank" >RIV/61989592:15310/11:33116857 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/ic201702j" target="_blank" >http://dx.doi.org/10.1021/ic201702j</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ic201702j" target="_blank" >10.1021/ic201702j</a>
Alternative languages
Result language
angličtina
Original language name
Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV)
Original language description
The reactions of iron(II) sulfate, 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole (abpt), and pentacyanidonitrosylferrate(II) or hexacyanidoplatinate(IV) resulted in the formation of one-dimensional iron(II) spin-crossover compounds [Fe(abpt)2(u-Fe(CN)5(NO)]n (1) and [Fe(abpt)2(u-Pt(CN)6]n (2) with the spin-transition critical temperature near or above room temperature accompanied by thermochromism. Furthermore, it has been proven that the critical temperature Tc is influenced by the type of dianionic polycyanidometallate within the series of discussed systems, and it changes in the sequence of [Fe(CN)5(NO)](2-) { {Pt(CN)6](2-) { [Ni(CN)4](2-) approximate to [Pd(CN)4}(2-) approximate to [Pt(CN)4](2-).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
50
Issue of the periodical within the volume
24
Country of publishing house
US - UNITED STATES
Number of pages
3
Pages from-to
12390-12392
UT code for WoS article
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EID of the result in the Scopus database
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