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Effects of doping with Zr and Hf on the structure and properties of Mo-Si-B coatings obtained by magnetron sputtering of composite targets

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU145612" target="_blank" >RIV/00216305:26620/22:PU145612 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0257897222000627?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0257897222000627?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.surfcoat.2022.128141" target="_blank" >10.1016/j.surfcoat.2022.128141</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Effects of doping with Zr and Hf on the structure and properties of Mo-Si-B coatings obtained by magnetron sputtering of composite targets

  • Original language description

    The Mo-Si-B, Mo-Zr-Si-B, and Mo-Hf-Si-B coatings were deposited by magnetron sputtering of the MoSi2-MoB, MoSi2-MoB-ZrB2 and MoSi2-MoB-HfB2 targets. The composition and structure of coatings were investigated by glow discharge optical emission spectroscopy, scanning electron microscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron and Raman spectroscopy. Mechanical properties were measured by nanoindentation method. The short-time oxidation resistance of coatings was evaluated at temperatures of 1100, 1300, and 1500 degrees C. The results showed that all coatings deposited onto alumina substrates were characterized by a dense columnar structure. Mo-Si-B coatings contained phases of hexagonal h-MoSi2 and amorphous a-MoB. With the addition of Zr and Hf, an increase in the lattice parameter and a decrease in the grain size of h-MoSi2 by 50 and 25%, respectively, were observed. The base Mo-Si-B coating had a high hardness of 30 GPa. The introduction of Zr and Hf led to a decrease in hardness by 24 and 20%, respectively. The Mo-Si-B coating was characterized by a minimal oxidation depth (<10 nm) at 1100 degrees C and 1300 degrees C, but a network of cracks that penetrated to the substrate was formed. Cracks on the surface of the Mo-Zr-Si-B and Mo-Hf-Si-B coatings were not observed; the formation of oxide layers, 0.3-2.0 mu m thick, was revealed. The oxidation resistance of coatings at temperature of 1500 degrees C increased in direction Mo-Si-B -> Mo-Hf-Si-B -> Mo-Zr-Si-B. The best results for the MoZr-Si-B coating were associated with a smaller grain size, higher thermal stability, and the formation of a protective layer based on SiO2 with the inclusion of ZrO2 crystallites.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20506 - Coating and films

Result continuities

  • Project

    <a href="/en/project/LM2018110" target="_blank" >LM2018110: CzechNanoLab research infrastructure</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    SURFACE & COATINGS TECHNOLOGY

  • ISSN

    1879-3347

  • e-ISSN

  • Volume of the periodical

    442

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    13

  • Pages from-to

    „128141“-„“

  • UT code for WoS article

    000822943100005

  • EID of the result in the Scopus database

    2-s2.0-85124319363