Molecularly "clicking" active moieties to germanium-based inorganic 2D materials

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU147077" target="_blank" >RIV/00216305:26620/22:PU147077 - isvavai.cz</a>

Alternative codes found

RIV/61989100:27240/22:10251366

Result on the web

<a href="https://pubs.rsc.org/en/content/articlelanding/2022/NR/D2NR04955D" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2022/NR/D2NR04955D</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d2nr04955d" target="_blank" >10.1039/d2nr04955d</a>

Result language

angličtina

Original language name

Molecularly "clicking" active moieties to germanium-based inorganic 2D materials

Original language description

Two dimensional materials beyond graphene are in forefront research. Two dimensional analogues of graphene of group 14, germanene, are of high importance for their electronic and optical properties. The commonly used deintercalation fabrication approach has reached a major bottleneck in the field due to the lack of versatility derived from the limited library of precursors available for 2D-Ge functionalization with terminal groups. Thus, a chemical procedure that would allow for the on-demand synthesis of functional 2D-Ge derivatives with tuned physicochemical features for task-specific applications is of utmost importance to advance in the field. To fill this gap, click chemistry is herein presented as a straightforward one-pot synthetic strategy to simply reach functional 2D-Ge derivatives by covalently assembling ad hoc thiol-rich active molecular components (R'-SH) upon commercially available allyl 2D-Ge (2D-Ge- CH2CH=CH2) by taking advantage of a photoinduced thiolene click reaction. Consequently, the combi -nation of molecular engineering and Ge-based 2D materials through click chemistry supposes a step forward towards the achievement of a new family of smart 2D-Ge-CH2CH2CH2S-R' derivatives with different (supra)molecular responsiveness, which goes beyond the state-of-the-art in the field. This approach of functionalization of 2D monoelemental post-graphene material germanene is highly innova-tive and shall provide universal way of functionalization of germananes.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project

<a href="/en/project/LM2018110" target="_blank" >LM2018110: CzechNanoLab research infrastructure</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2022

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Nanoscale

ISSN

2040-3364

e-ISSN

2040-3372

Volume of the periodical

14

Issue of the periodical within the volume

48

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

18167-18174

UT code for WoS article

000898090300001

EID of the result in the Scopus database

2-s2.0-85144050022