Alkali Metal Arenides as a Universal Synthetic Tool for Layered 2D Germanene Modification
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43918150" target="_blank" >RIV/60461373:22310/19:43918150 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201910654" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201910654</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201910654" target="_blank" >10.1002/anie.201910654</a>
Alternative languages
Result language
angličtina
Original language name
Alkali Metal Arenides as a Universal Synthetic Tool for Layered 2D Germanene Modification
Original language description
The rediscovery of graphene in 2004 has started an enormous chase in the research of 2D materials. A new family of layered 2D materials consisting of the 14th group elements beyond carbon has already been reported. Here, a new methodology in germanene chemistry is presented using germanane (Ge6H6) as a stable and easily accessible starting material for effective synthesis of novel germanene derivatives. The modification procedure utilizing strong bases-alkali metal arenides-for deprotonation of germanane and its subsequent functionalization with p-nitrobenzyl bromide is described. Functionalization of germanene is confirmed by FT-IR, Raman, and XPS spectroscopy as well as by X-ray diffraction analysis.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GX19-26910X" target="_blank" >GX19-26910X: The chemistry in two dimensions - beyond graphene</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie-International Edition
ISSN
1433-7851
e-ISSN
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Volume of the periodical
58
Issue of the periodical within the volume
46
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
16517-16522
UT code for WoS article
000489496200001
EID of the result in the Scopus database
2-s2.0-85073938597