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Periodic Table Exploration of MXenes for Efficient Electrochemical Nitrate Reduction to Ammonia

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F26%3A0198215" target="_blank" >RIV/00216305:26620/26:0198215 - isvavai.cz</a>

  • Alternative codes found

    RIV/62156489:43210/25:43926652 RIV/61989592:15640/25:73630490 RIV/61989100:27740/25:10257027

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/10.1002/smll.202410105" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/smll.202410105</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/smll.202410105" target="_blank" >10.1002/smll.202410105</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Periodic Table Exploration of MXenes for Efficient Electrochemical Nitrate Reduction to Ammonia

  • Original language description

    Applying electrochemical nitrate reduction reaction (NO3RR) to produce ammonia offers a sustainable alternative to the energy-intensive Haber-Bosch process, which is crucial for clean energy and agricultural applications. While 2D MXenes hold great promise as electrocatalysts for NO3RR, their application for ammonia production remains underexplored. This study combines experimental and theoretical approaches to evaluate the catalytic performance of a series of MXenes with different central metal atoms for NO3RR. Among the materials studied (Ti3C2Tx, Ti3CNTx, Ti2CTx, V2CTx, Cr2CTx, Nb2CTx, and Ta2CTx), Ti3-based MXenes exhibit superior faradaic efficiency, ammonia yield rate, and stability. Density functional theory calculations offer further insights explaining the structure-activity-based observations. This research establishes a foundation for future studies aimed at leveraging MXenes for electrochemical nitrate reduction for green synthesis of ammonia.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    21001 - Nano-materials (production and properties)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Small

  • ISSN

    1613-6810

  • e-ISSN

    1613-6829

  • Volume of the periodical

    21

  • Issue of the periodical within the volume

    10

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    14

  • Pages from-to

  • UT code for WoS article

    001424471300001

  • EID of the result in the Scopus database

    2-s2.0-86000434632