Organosilicon and -germanium Hydrides in Catalyst-Free Hydrometallation Reactions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F28778758%3A_____%2F17%3AN0000012" target="_blank" >RIV/28778758:_____/17:N0000012 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/17:39911687
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701142" target="_blank" >https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701142</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201700630" target="_blank" >10.1002/ejic.201700630</a>
Alternative languages
Result language
angličtina
Original language name
Organosilicon and -germanium Hydrides in Catalyst-Free Hydrometallation Reactions
Original language description
Group 14 element hydrides in oxidation states +IV and +II can undergo hydroelementation reactions through addition of the E–H bonds to unsaturated bonds. The neutral group 14 element(IV) hydrides do not have suitable vacant valence orbitals and as a result are only poorly effective for the hydroelementation of unsaturated bonds without addition of any initiators; however, their low-valent analogues in oxidation state +II seem to be effective in the hydroelementation of unsaturated bonds under mild conditions. The goal of this paper is to overview examples of catalyst-free hydrosilylation and hydrogermylation reactions to highlight current knowledge about uncatalysed reactions between silicon- or germanium-(II and IV) hydrides and organic molecules containing unsaturated bonds.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA15-07091S" target="_blank" >GA15-07091S: Uncatalyzed Hydrosilylations Induced by N→Si Coordination</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
1099-0682
Volume of the periodical
2017
Issue of the periodical within the volume
42
Country of publishing house
DE - GERMANY
Number of pages
12
Pages from-to
4887-4898
UT code for WoS article
000415362400001
EID of the result in the Scopus database
2-s2.0-85033777502