Triorganostannyl(IV) benzoates with pendulous framework appended with ferrocene scaffold
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F28778758%3A_____%2F19%3AN0000004" target="_blank" >RIV/28778758:_____/19:N0000004 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0022328X18309938" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0022328X18309938</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2018.12.009" target="_blank" >10.1016/j.jorganchem.2018.12.009</a>
Alternative languages
Result language
angličtina
Original language name
Triorganostannyl(IV) benzoates with pendulous framework appended with ferrocene scaffold
Original language description
A series of four new long chain triorganotin(IV) esters containing a diazenyl- and an imino-groups appended with ferrocene scaffold were designed and synthesized. Ferrocene based metallo proligands H'HFcL1 and H'HFcL2 were obtained by reacting isomeric 3-/4-ferrocenylanilines with 2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1-diazenyl]benzoic acid, which upon reactions with appropriate triorganotin(IV) precursors yielded compounds namely, [nBu3Sn(HFcL1)] 1, [Ph3Sn(HFcL1) 2, [nBu3Sn(HFcL2)] 3 and [Ph3Sn(HFcL2) 4. Compounds 1e4 have been characterized by elemental analysis and their spectroscopic properties were investigated using IR, UV-Vis and NMR spectroscopic techniques. The molecular structures of H'HFcL1 and two representative heterobimetallic compounds 3 and 4 have been determined by X-ray crystallography. Compound 3 is a 1D polymer and 4 is a discrete molecule; their structural differences relative to those of H'HFcL1 clearly indicate the influence of the binding of the tin cluster. The redox properties of the metallo pro-ligands and their compounds were also investigated by cyclic voltammetry.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
1872-8561
Volume of the periodical
882
Issue of the periodical within the volume
1.3.2019
Country of publishing house
CH - SWITZERLAND
Number of pages
9
Pages from-to
33-41
UT code for WoS article
000456533700005
EID of the result in the Scopus database
2-s2.0-85059556758