Exploring Imidazole Binding Flexibility in 2D and 3D Frameworks Using Hypercoordinated Triorganotin Carboxylates Featuring a Nitrogen-Rich Ligand with Benzoic Acid, Diazenyl, and Imidazole Functionalities: Insights into Sn - N, N → Sn, and N - H⋅⋅⋅X (X = N, O) Interactions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62690094%3A18470%2F24%3A50021650" target="_blank" >RIV/62690094:18470/24:50021650 - isvavai.cz</a>
Result on the web
<a href="https://link.springer.com/article/10.1007/s10904-024-03129-w" target="_blank" >https://link.springer.com/article/10.1007/s10904-024-03129-w</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10904-024-03129-w" target="_blank" >10.1007/s10904-024-03129-w</a>
Alternative languages
Result language
angličtina
Original language name
Exploring Imidazole Binding Flexibility in 2D and 3D Frameworks Using Hypercoordinated Triorganotin Carboxylates Featuring a Nitrogen-Rich Ligand with Benzoic Acid, Diazenyl, and Imidazole Functionalities: Insights into Sn - N, N → Sn, and N - H⋅⋅⋅X (X = N, O) Interactions
Original language description
The multitopic heterofunctional pro-ligand 4-[(E)-(1H-imidazol-2-yl)diazenyl]benzoic acid (H ' HL) was synthesized by diazotization of 4-aminobenzoic acid followed by coupling with imidazole. Reactions of H ' HL (where H = imidazole proton and H ' = carboxylic acid proton) with the triorganotin precursors (Pr3SnCl)-Pr-n, ((Bu3Sn)-Bu-n)(2)O and Ph3SnOH provided three hypercoordinated triorganotin complexes, viz., [(Pr3Sn)-Pr-n(mu(4)-L)(SnPr3)-Pr-n](n)& sdot;1/8nEtOH (1), [(Bu3Sn)-Bu-n(mu-HL)](n) (2) and [Ph3Sn(HL)]& sdot;0.5C(6)H(6) (3), with complex 2D and 3D frameworks based on Sn - O, O -> Sn, Sn - N and N -> Sn metal-ligand bonds as well as N - H & sdot;& sdot;& sdot;N, N - H & sdot;& sdot;& sdot;O and pi-interactions. The compositions and structures of 1-3 in solution and in the solid-state were unambiguously established by NMR (H-1, C-13, Sn-119) and IR spectroscopy, UV-Vis spectral analysis, high-resolution mass spectrometry (HRMS) and single-crystal X-ray diffraction (scXRD) studies accompanied by Hirshfeld surface maps and 2D fingerprint plots.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Inorganic and Organometallic Polymers and Materials
ISSN
1574-1443
e-ISSN
1574-1451
Volume of the periodical
34
Issue of the periodical within the volume
7
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
19
Pages from-to
3281-3299
UT code for WoS article
001234282300001
EID of the result in the Scopus database
2-s2.0-85194566962