Effect of Waste Metal and Chamotte Fillers on the Thermal and Mechanical Properties of Geopolymer Composites for Energy Storage Applications

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24210%2F25%3A00014026" target="_blank" >RIV/46747885:24210/25:00014026 - isvavai.cz</a>

Result on the web

<a href="https://doi.org/10.3390/ma18163853" target="_blank" >https://doi.org/10.3390/ma18163853</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/ma18163853" target="_blank" >10.3390/ma18163853</a>

Result language

angličtina

Original language name

Effect of Waste Metal and Chamotte Fillers on the Thermal and Mechanical Properties of Geopolymer Composites for Energy Storage Applications

Original language description

This study investigates the effects of varying filler content on the thermal and mechanical performance of metakaolinite-based geopolymer composites designed for thermal energy storage applications. The composites were formulated using a geopolymer binder, combined with a thermally stable filler (ground chamotte) and a thermal energy storage filler (waste steel chips) in different proportions. Chamotte content within the binder matrix (binder + chamotte) ranged from 20 to 40 wt.%, while steel chip content varied from 0 to 40 wt.% of the total composite mass. The thermal properties of the composites were evaluated at room temperature and compared with conventional reference materials, including Ultraboard, chamotte brick, and magnetite brick. Mechanical performance, specifically flexural and compressive strength, was evaluated at room temperature and after exposure to elevated temperatures (800 and 1100 °C), followed by two cooling regimes, slow furnace cooling and rapid water quenching. Microstructural characterization via optical microscopy was used to examine filler dispersion and matrix–filler interactions. The results showed that the thermal effusivity of the optimized composites exceeded that of chamotte brick by more than 50%. The highest flexural (12.68 MPa) and compressive (86.18 MPa) strengths were achieved in the composite containing 20 wt.% steel chips, prior to thermal exposure. Microstructural observations revealed the diverse geometry of the steel chips and arrangement of the chamotte particles. These findings highlight the potential of incorporating metallic waste materials into geopolymer systems to develop multifunctional composites with improved thermal storage capacity and mechanical resilience.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

20500 - Materials engineering

Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2025

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

MATERIALS>

ISSN

1996-1944

e-ISSN

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Volume of the periodical

18

Issue of the periodical within the volume

16

Country of publishing house

CH - SWITZERLAND

Number of pages

21

Pages from-to

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UT code for WoS article

001558003500001

EID of the result in the Scopus database

2-s2.0-105014324102