All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Ni nanowires decorated with Pd nanoparticles as an efficient nanocatalytic system for Suzuki coupling of anisole derivatives

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24620%2F23%3A00011524" target="_blank" >RIV/46747885:24620/23:00011524 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S2352507X23001154" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2352507X23001154</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.nanoso.2023.101052" target="_blank" >10.1016/j.nanoso.2023.101052</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Ni nanowires decorated with Pd nanoparticles as an efficient nanocatalytic system for Suzuki coupling of anisole derivatives

  • Original language description

    Suzuki-Miyaura reaction enables the formation of biaryl compounds containing diverse functional groups. This work reports the development of a nanocatalytic system, which enhances the coupling of anisole derivatives using this reaction framework. Composite nanocatalysts were prepared by decorating nickel nanowires (Ni NWs) made in-house with spherical palladium nanoparticles (Pd NPs). Sonochemical deposition of noble catalytic centers on metallic nanowires proved to be fast and effective under mild conditions. Precise control of the concentration of Pd NPs on the nanowire surface enabled studying the impact of the content of noble metal on the reaction course. The lowest evaluated load of Pd (0.34 %) exhibited the best catalytic performance. Moreover, it was noted that the application of microwaves considerably increased the catalytic activity of the system due to the formation of hot spots on Pd NPs. As a result, the reaction times were shortened substantially without negatively influencing the yields of the transformations. The proposed novel approach for nanocatalyst design should inspire further studies in modern organic chemistry, especially since the proposed catalytic system is highly efficient and entirely reusable.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>SC</sub> - Article in a specialist periodical, which is included in the SCOPUS database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Nano-structures & nano-objects

  • ISSN

    2352-507X

  • e-ISSN

  • Volume of the periodical

    36

  • Issue of the periodical within the volume

    October

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    12

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database

    2-s2.0-85176152773