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On crystallization and oxidation behavior of Zr54Cu46 and Zr27Hf27Cu46 thin-film metallic glasses compared to a crystalline Zr54Cu46 thin-film alloy

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23520%2F18%3A43952055" target="_blank" >RIV/49777513:23520/18:43952055 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1016/j.jnoncrysol.2018.09.004" target="_blank" >https://doi.org/10.1016/j.jnoncrysol.2018.09.004</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jnoncrysol.2018.09.004" target="_blank" >10.1016/j.jnoncrysol.2018.09.004</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    On crystallization and oxidation behavior of Zr54Cu46 and Zr27Hf27Cu46 thin-film metallic glasses compared to a crystalline Zr54Cu46 thin-film alloy

  • Original language description

    Amorphous Zr54Cu46 and Zr27Hf27Cu46 thin-film metallic glasses were prepared by non-reactive magnetron co-sputtering of Zr, Hf and Cu in pure argon. Several as-deposited Zr54Cu46 films were post-annealed in high vacuum to create a crystalline thin-film alloy of the identical composition. The non-isothermal crystallization behavior of the amorphous Zr54Cu46 and Zr27Hf27Cu46 films and the effect of a substitution of Hf for Zr on the crystallization process were studied by differential scanning calorimetry. The activation energy of the crystallization was obtained by the Kissinger–Akahira–Sunose method. The results show that the activation energy of the Zr27Hf27Cu46 film was higher for all conversion fractions, which indicates that the substitution of Hf for Zr enhances the thermal stability of the glassy state. Considerable attention was also paid to the isothermal oxidation behavior of the amorphous and crystalline Zr54Cu46, and amorphous Zr27Hf27Cu46 films investigated by thermogravimetric analysis. It was shown that all oxidation curves in the temperature range from 400 to 575 °C obeyed the parabolic law. The activation energy of the oxidation process determined by the Arrhenius equation for the oxidation rate constants was found to be the highest for the Zr27Hf27Cu46 film, which indicates that its surface oxide layer is a more effective barrier against the diffusion of species.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20506 - Coating and films

Result continuities

  • Project

    <a href="/en/project/GA16-18183S" target="_blank" >GA16-18183S: Advanced surface coatings with enhanced properties and thermal stability</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    JOURNAL OF NON-CRYSTALLINE SOLIDS

  • ISSN

    0022-3093

  • e-ISSN

  • Volume of the periodical

    500

  • Issue of the periodical within the volume

    15 NOV 2018

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    7

  • Pages from-to

    475-481

  • UT code for WoS article

    000447096600061

  • EID of the result in the Scopus database

    2-s2.0-85053296913