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Electronic structure, effective mass, and optical dispersion of 2-mercapto-5-methyl-1,3,4-thiadiazole: density functional theory calculations

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23640%2F14%3A43922654" target="_blank" >RIV/49777513:23640/14:43922654 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.mssp.2014.05.054" target="_blank" >http://dx.doi.org/10.1016/j.mssp.2014.05.054</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.mssp.2014.05.054" target="_blank" >10.1016/j.mssp.2014.05.054</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electronic structure, effective mass, and optical dispersion of 2-mercapto-5-methyl-1,3,4-thiadiazole: density functional theory calculations

  • Original language description

    Density functional theory was used to calculate the electronic band structure, effective mass, and optical dispersion of 2-mercapto-5-methyl-1,3,4-thiadiazole (MMTD). The exchange correlation potential was treated using the local density approximation, generalized gradient approximation, and modified Becke Johnson approximation. The calculated band structure shows that MMTD has a direct energy bandgap. The partial density of states revealed strong hybridization between N p, C p, N s, and H s orbitals. The electronic charge density distribution confirmed partial ionic and strong covalent C-N, C-C, C-H, and N-N bonds. We also calculated the optical dielectric function and related optical properties (refractive index, extinction coefficient, absorption coefficient, and reflectivity).

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BE - Theoretical physics

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/ED2.1.00%2F03.0088" target="_blank" >ED2.1.00/03.0088: Centre of the New Technologies and Materials</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Materials Science in Semiconductor Processing

  • ISSN

    1369-8001

  • e-ISSN

  • Volume of the periodical

    26

  • Issue of the periodical within the volume

    říjen 2014

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

    649-656

  • UT code for WoS article

  • EID of the result in the Scopus database