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First-Principles Calculations of Structural, Elastic, Electronic, and Optical Properties of Perovskite-type KMgH(3) Crystals: Novel Hydrogen Storage Material

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12640%2F11%3A43882661" target="_blank" >RIV/60076658:12640/11:43882661 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1021/jp111382h" target="_blank" >http://dx.doi.org/10.1021/jp111382h</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/jp111382h" target="_blank" >10.1021/jp111382h</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    First-Principles Calculations of Structural, Elastic, Electronic, and Optical Properties of Perovskite-type KMgH(3) Crystals: Novel Hydrogen Storage Material

  • Original language description

    We report a first-principles study of structural and phase stability in three different structures of perovskite-types KMgH(3) according to H position. While electronic and optical properties were measured only for stable perovskite-type KMgH(3), our calculated structural parameters are found in good agreement with experiment and other theoretical results. We also study the electronic charge density space distribution contours in the (200), (101), and (100) crystallographic planes, which gives better insight picture of chemical bonding between K-H, K-Mg-H, and Mg-H. Moreover, we have calculated the electronic band structure dispersion, total, and partial density of electron states to study the band gap origin and the contribution of s-band of H, s andp-band of Mg in the valence band, and d-band of K in the conduction band. Furthermore, optical features such as dielectric functions, refractive indices, extinction coefficient, optical reflectivity, absorption coefficients, optical condu

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BO - Biophysics

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/ED2.1.00%2F01.0024" target="_blank" >ED2.1.00/01.0024: South Bohemian Research Center of Aquaculture and Biodiversity of Hydrocenoses</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Physical Chemistry B

  • ISSN

    1520-6106

  • e-ISSN

  • Volume of the periodical

    115

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

    2836-2841

  • UT code for WoS article

    000288644700018

  • EID of the result in the Scopus database