Dynamic cooperative behavior of constituting species at the glass transition vicinity

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23640%2F15%3A43927195" target="_blank" >RIV/49777513:23640/15:43927195 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1007/s10973-015-4422-6" target="_blank" >http://dx.doi.org/10.1007/s10973-015-4422-6</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10973-015-4422-6" target="_blank" >10.1007/s10973-015-4422-6</a>

Result language

angličtina

Original language name

Dynamic cooperative behavior of constituting species at the glass transition vicinity

Original language description

Liquid and its freeze-in form of constrained glasses are assumed to consist from both the mechanically divided structure formed by blocks and the individual semi-evaporated units subjected to nonlinear anharmonic motions of high amplitudes. The sequenceof characteristic temperatures is classified from the boiling point temperature T b through crossover temperature T cr, transition temperature of glassy state T g and down to the Vogel's temperature T v, recognizing that T b GREATER-THAN OR EQUAL TO T crGREATER-THAN OR EQUAL TO T g GREATER-THAN OR EQUAL TO T v and taking into account distinct characteristics of vibration modes at different temperatures. Above T cr, the termination of bridge-over effect of blocks is assumed and the level of shear modulus contributed by bridging falls down to zero. The Angell's famous equation on fragility dealing with the shear viscosity derivative relatively to inverse absolute temperature is replaced by the thermal sensitivity seeing it as an alternat

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BJ - Thermodynamics

OECD FORD branch

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Project

<a href="/en/project/ED2.1.00%2F03.0088" target="_blank" >ED2.1.00/03.0088: Centre of the New Technologies and Materials</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Thermal Analysis and Calorimetry

ISSN

1388-6150

e-ISSN

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Volume of the periodical

120

Issue of the periodical within the volume

1

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

74

Pages from-to

167-173

UT code for WoS article

000352139800020

EID of the result in the Scopus database

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