All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Distinct Photophysics of the Isomers of B18H22 Explained

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12310%2F12%3A43884437" target="_blank" >RIV/60076658:12310/12:43884437 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388980:_____/12:00377475 RIV/61388955:_____/12:00377475

  • Result on the web

    <a href="http://dx.doi.org/10.1021/ic201726k" target="_blank" >http://dx.doi.org/10.1021/ic201726k</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/ic201726k" target="_blank" >10.1021/ic201726k</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Distinct Photophysics of the Isomers of B18H22 Explained

  • Original language description

    The photophysics of the two isomers of octadecaborane(22), anti- and syn-B18H22, have been studied by UV-vis spectroscopic techniques and theoretical computational methods. In air-saturated hexane, anti-B18H22 shows fluorescence with a high quantum yield, Phi(F) = 0.97, and singlet oxygen O-2((1)Delta(g)) production (Phi(Delta) similar to 0.008). Conversely, isomer syn-B18H22 shows no measurable fluorescence, instead displaying much faster, picosecond non-adiative decay of excited singlet states. Computed potential energy hypersurfaces (PEHs) for both isomers rationalize these data, pointing to a deep S-1 minimum for anti-B18H22 and a conical intersection (CI) between its S-0 and S-1 states that lies 0.51 eV higher in energy. Such an energy barrier tononradiative relaxation is not present in the PEH of syn-B18H22, and the system therefore has sufficient initial energy on excitation to reach the (S-0/S-1) CI and to then decay to the ground state without fluorescence. The computational

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BO - Biophysics

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Inorganic Chemistry

  • ISSN

    0020-1669

  • e-ISSN

  • Volume of the periodical

    51

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    1471-1479

  • UT code for WoS article

    000300474700038

  • EID of the result in the Scopus database