Bismuth A(3)-Corroles: Useful Precursors for the Development of meso-Substituted Free-Base Corroles

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12310%2F14%3A43887262" target="_blank" >RIV/60076658:12310/14:43887262 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1055/s-0034-1379012" target="_blank" >http://dx.doi.org/10.1055/s-0034-1379012</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1055/s-0034-1379012" target="_blank" >10.1055/s-0034-1379012</a>

Result language
angličtina
Original language name
Bismuth A(3)-Corroles: Useful Precursors for the Development of meso-Substituted Free-Base Corroles
Original language description
Systematic studies on regioselective functionalization reactions employing oxygen-, nitrogen-, and sulfur-containing nucleophiles with bismuth A(3)-corroles under the influence of a strong non-nucleophilic base are reported. In the case of the thiols anddithiols a high-yielding reaction procedure was established to obtain mono-, di-, and tri-functionalized corroles at room temperature within short reaction times. The described method offers a possibility to attach bifunctional linker molecules to the para-position of the meso-pentafluorophenyl groups at positions 5, 10, and 15 of the corrole macrocycle. The described reaction strategy may serve as a versatile protocol for the covalent binding of corroles to proteins or antibodies and may be utilized to attach corroles on, for example, gold or titanium surfaces to study surface-supported reactions.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CE - Biochemistry
OECD FORD branch
—

Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)